At the moment there isnt a way to set a specific P+P charge per product.
One way to get around this, could be to do you shipping by weight, so you could create different shipping charges against different weights of products, you set the weight of a product up under the General tab in the Product Details.
If a certain product had a very high weight, then you could give this high weight the P+P charges you are wanting in View | Business Settings | Shipping and Handling.
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