For a 10% shipping charge, set the 'Basis' to 'Value' and then enter a single row in the shipping grid as follows:
Value | Cost
£0.10 | £0.01
Then set excess to charge an additional £0.01 for every £0.10.
Value | Cost
£0.10 | £0.01
Then set excess to charge an additional £0.01 for every £0.10.